Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries.

Cui, Zhuangzhuang; Jia, Zhuangzhuang; Ruan, Digen; Nian, Qingshun; Fan, Jiajia; Chen, Shunqiang; He, Zixu; Wang, Dazhuang et al. · Nat Commun · 2024

basic_science · Level V

Where this comes from

Abstract

Constraining the electrochemical reactivity of free solvent molecules is pivotal for developing high-voltage lithium metal batteries, especially for ether solvents with high Li metal compatibility but low oxidation stability ( <4.0 V vs Li<sup>+</sup>/Li). The typical high concentration electrolyte approach relies on nearly saturated Li<sup>+</sup> coordination to ether molecules, which is confronted with severe side reactions under high voltages ( >4.4 V) and extensive exothermic reactions between Li metal and reactive anions. Herein, we propose a molecular anchoring approach to restrict the interfacial reactivity of free ether solvents in diluted electrolytes. The hydrogen-bonding interactions from the anchoring solvent effectively suppress excessive ether side reactions and enhances the stability of nickel rich cathodes at 4.7 V, despite the extremely low Li<sup>+</sup>/ether molar ratio (1:9) and the absence of typical anion-derived interphase. Furthermore, the exothermic processes under thermal abuse conditions are mitigated due to the reduced reactivity of anions, which effectively postpones the battery thermal runaway.