Roll-to-roll, high-resolution 3D printing of shape-specific particles.

Kronenfeld, Jason M; Rother, Lukas; Saccone, Max A; Dulay, Maria T; DeSimone, Joseph M · Nature · 2024

basic_science · Level V

Where this comes from

Abstract

Particle fabrication has attracted recent attention owing to its diverse applications in bioengineering<sup>1,2</sup>, drug and vaccine delivery<sup>3-5</sup>, microfluidics<sup>6,7</sup>, granular systems<sup>8,9</sup>, self-assembly<sup>5,10,11</sup>, microelectronics<sup>12,13</sup> and abrasives<sup>14</sup>. Herein we introduce a scalable, high-resolution, 3D printing technique for the fabrication of shape-specific particles based on roll-to-roll continuous liquid interface production (r2rCLIP). We demonstrate r2rCLIP using single-digit, micron-resolution optics in combination with a continuous roll of film (in lieu of a static platform), enabling the rapidly permutable fabrication and harvesting of shape-specific particles from a variety of materials and with complex geometries, including geometries not possible to achieve with advanced mould-based techniques. We demonstrate r2rCLIP production of mouldable and non-mouldable shapes with voxel sizes as small as 2.0 × 2.0 µm<sup>2</sup> in the print plane and 1.1 ± 0.3 µm unsupported thickness, at speeds of up to 1,000,000 particles per day. Such microscopic particles with permutable, intricate designs enable direct integration within biomedical, analytical and advanced materials applications.