Regulating Benzene Ring Number as Connector in Covalent Organic Framework for Boosting Photosynthesis of H<sub>2</sub>O<sub>2</sub> from Seawater.
basic_science · Level V
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- Record sourced from PubMed, PMID 38488397.
- Also identified by DOI 10.1021/acs.nanolett.4c00628.
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Abstract
Photosynthesis of H<sub>2</sub>O<sub>2</sub> from seawater represents a promising pathway to acquire H<sub>2</sub>O<sub>2</sub>, but it is still restricted by the lack of a highly active photocatalyst. In this work, we propose a convenient strategy of regulating the number of benzene rings to boost the catalytic activity of materials. This is demonstrated by ECUT-COF-31 with adding two benzene rings as the connector, which can result in 1.7-fold enhancement in the H<sub>2</sub>O<sub>2</sub> production rate relative to ECUT-COF-30 with just one benzene ring as the connector. The reason for enhancement is mainly due to the release of *OOH from the surface of catalyst and the final formation of H<sub>2</sub>O<sub>2</sub> being easier in ECUT-COF-31 than in ECUT-COF-30. Moreover, ECUT-COF-31 provides a stable photogeneration of H<sub>2</sub>O<sub>2</sub> for 70 h, and a theoretically remarkable H<sub>2</sub>O<sub>2</sub> production of 58.7 mmol per day from seawater using one gram of photocatalyst, while the cost of the used raw material is as low as 0.24 $/g.