Ligand efficacy modulates conformational dynamics of the µ-opioid receptor.

Zhao, Jiawei; Elgeti, Matthias; O'Brien, Evan S; Sár, Cecília P; Ei Daibani, Amal; Heng, Jie; Sun, Xiaoou; White, Elizabeth et al. · Nature · 2024

basic_science · Level V

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Abstract

The µ-opioid receptor (µOR) is an important target for pain management<sup>1</sup> and molecular understanding of drug action on µOR will facilitate the development of better therapeutics. Here we show, using double electron-electron resonance and single-molecule fluorescence resonance energy transfer, how ligand-specific conformational changes of µOR translate into a broad range of intrinsic efficacies at the transducer level. We identify several conformations of the cytoplasmic face of the receptor that interconvert on different timescales, including a pre-activated conformation that is capable of G-protein binding, and a fully activated conformation that markedly reduces GDP affinity within the ternary complex. Interaction of β-arrestin-1 with the μOR core binding site appears less specific and occurs with much lower affinity than binding of G<sub>i</sub>.

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