Presodiation Architected Robust Surface Enables Packaging Optimal Performance of Sodium-Ion Batteries.
basic_science · Level V
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- Record sourced from PubMed, PMID 38805022.
- Also identified by DOI 10.1021/acs.nanolett.4c00842.
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Abstract
Presodiation has shown great promise in compensating sodium storage losses. In the absence of a mechanistic understanding of how presodiation affects the surface of an electrode material, packaging optimization is restricted. Focusing on interfaces, we illustrate the working principle of presodiation in virtue of short-circuiting internal circuits. The presodiated carbon nanotubes (PS-CNTs) provide a thin, denser, and more robust solid electrolyte interfacial layer, enabling a high initial Coulombic efficiency (ICE), high power density, and cycling stability with the merits of uniformly distributed NaF. As a result, our assembled sodium-ion battery (SIB) full cell with PS-CNT has an ICE of 91.6% and an energy density of 226 Wh kg<sup>-1</sup>, which was superior to the pristine CNT control electrode (ICE of 42.9% and energy density of 163 Wh kg<sup>-1</sup>). The gained insights can be practically applied to directly promote the commercial uses of carbon-based materials in sodium-ion batteries.