Continuous sterane and phytane δ<sup>13</sup>C record reveals a substantial pCO<sub>2</sub> decline since the mid-Miocene.

Witkowski, Caitlyn R; von der Heydt, Anna S; Valdes, Paul J; van der Meer, Marcel T J; Schouten, Stefan; Sinninghe Damsté, Jaap S · Nat Commun · 2024

basic_science · Level V

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Abstract

Constraining the relationship between temperature and atmospheric concentrations of carbon dioxide (pCO<sub>2</sub>) is essential to model near-future climate. Here, we reconstruct pCO<sub>2</sub> values over the past 15 million years (Myr), providing a series of analogues for possible near-future temperatures and pCO<sub>2</sub>, from a single continuous site (DSDP Site 467, California coast). We reconstruct pCO<sub>2</sub> values using sterane and phytane, compounds that many phytoplankton produce and then become fossilised in sediment. From 15.0-0.3 Myr ago, our reconstructed pCO<sub>2</sub> values steadily decline from 650 ± 150 to 280 ± 75 ppmv, mirroring global temperature decline. Using our new range of pCO<sub>2</sub> values, we calculate average Earth system sensitivity and equilibrium climate sensitivity, resulting in 13.9 °C and 7.2 °C per doubling of pCO<sub>2</sub>, respectively. These values are significantly higher than IPCC global warming estimations, consistent or higher than some recent state-of-the-art climate models, and consistent with other proxy-based estimates.