A Soldering Flux Tackles Complex Defects Chemistry in Sn-Pb Perovskite Solar Cells.
basic_science · Level V
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- Record sourced from PubMed, PMID 38978417.
- Also identified by DOI 10.1002/adma.202405807.
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Abstract
Developing tin-lead (Sn-Pb) narrow-bandgap perovskites is crucial for the deployment of all-perovskite tandem solar cells, which can help to exceed the limits of single-junction photovoltaics. However, the Sn-Pb perovskite suffers from a large number of bulk traps and interfacial nonradiative recombination centers, with unsatisfactory open-circuit voltage and the consequent device efficiency. Herein, for the first time, it is shown that abietic acid (AA), a commonly used flux for metal soldering, effectively tackles complex defects chemistry in Sn-Pb perovskites. The conjugated double bond within AA molecule plays a key role for self-elimination of Sn<sup>4+</sup>-Pb<sup>0</sup> defects pair, via a redox process. In addition, C═O group is able to coordinate with Sn<sup>2+</sup>, leading to the improved antioxidative stability of Sn-Pb perovskites. Consequently, a ten-times longer carrier lifetime is observed, and the defects-associated dual-peak emission feature at low temperature is significantly inhibited. The resultant device achieves a power conversion efficiency improvement from 22.28% (Ref) to 23.42% with respectable stability under operational and illumination situations.