Controlling <sup>229</sup>Th isomeric state population in a VUV transparent crystal.

Hiraki, Takahiro; Okai, Koichi; Bartokos, Michael; Beeks, Kjeld; Fujimoto, Hiroyuki; Fukunaga, Yuta; Haba, Hiromitsu; Kasamatsu, Yoshitaka et al. · Nat Commun · 2024

basic_science · Level V

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Abstract

The radioisotope thorium-229 (<sup>229</sup>Th) is renowned for its extraordinarily low-energy, long-lived nuclear first-excited state. This isomeric state can be excited by vacuum ultraviolet (VUV) lasers and <sup>229</sup>Th has been proposed as a reference transition for ultra-precise nuclear clocks. To assess the feasibility and performance of the nuclear clock concept, time-controlled excitation and depopulation of the <sup>229</sup>Th isomer are imperative. Here we report the population of the <sup>229</sup>Th isomeric state through resonant X-ray pumping and detection of the radiative decay in a VUV transparent <sup>229</sup>Th-doped CaF<sub>2</sub> crystal. The decay half-life is measured to 447(25) s, with a transition wavelength of 148.18(42) nm and a radiative decay fraction consistent with unity. Furthermore, we report a new "X-ray quenching" effect which allows to de-populate the isomer on demand and effectively reduce the half-life. Such controlled quenching can be used to significantly speed up the interrogation cycle in future nuclear clock schemes.