Alkali cation stabilization of defects in 2D MXenes at ambient and elevated temperatures.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 39069542.
- Also identified by DOI 10.1038/s41467-024-50713-2 and PMC identifier 11284208.
- Licence recorded as CC BY-NC-ND.
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Abstract
Transition metal carbides have been adopted in energy storage, conversion, and extreme environment applications. Advancements in their 2D counterparts, known as MXenes, enable the design of unique structures at the ~1 nm thickness scale. Alkali cations have been essential in MXenes manufacturing processing, storage, and applications, however, exact interactions of these cations with MXenes are not fully understood. In this study, using Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>, Mo<sub>2</sub>TiC<sub>2</sub>T<sub>x</sub>, and Mo<sub>2</sub>Ti<sub>2</sub>C<sub>3</sub>T<sub>x</sub> MXenes, we present how transition metal vacancy sites are occupied by alkali cations, and their effect on MXene structure stabilization to control MXene's phase transition. We examine this behavior using in situ high-temperature x-ray diffraction and scanning transmission electron microscopy, ex situ techniques such as atomic-layer resolution secondary ion mass spectrometry, and density functional theory simulations. In MXenes, this represents an advance in fundamentals of cation interactions on their 2D basal planes for MXenes stabilization and applications. Broadly, this study demonstrates a potential new tool for ideal phase-property relationships of ceramics at the atomic scale.