High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 39117719.
- Also identified by DOI 10.1038/s41467-024-51058-6 and PMC identifier 11310198.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Superparaelectrics are considered promising candidate materials for achieving superior energy storage capabilities. However, due to the complicated local structural design, simultaneously achieving high recoverable energy density (W<sub>rec</sub>) and energy storage efficiency (η) under high electric fields remains a challenge in bulk superparaelectrics. Here, we propose utilizing entropy engineering to disrupt long-range ferroic orders into local polymorphic distortion disorder with multiple BO<sub>6</sub> tilt types and diverse heterogeneous polarization configurations. This strategy reduces the switching barriers, thereby facilitating the emergence of superparaelectric behaviors with ideal polarization forms. Furthermore, it enables high polarization response, negligible remnant polarization, delayed polarization saturation, and enhanced breakdown electric fields (E<sub>b</sub>) in high-entropy superparaelectrics. Consequently, an extraordinary W<sub>rec</sub> of 15.48 J cm<sup>-3</sup> and an ultrahigh η of 90.02% are achieved at a high E<sub>b</sub> of 710 kV cm<sup>-1</sup>, surpassing the comprehensive energy storage performance of previously reported bulk superparaelectrics. This work demonstrates that entropy engineering is a viable strategy for designing high-performance superparaelectrics.