Long- and short-term coupling of sea surface temperature and atmospheric CO<sub>2</sub> during the late Paleocene and early Eocene.

Harper, Dustin T; Hönisch, Bärbel; Bowen, Gabriel J; Zeebe, Richard E; Haynes, Laura L; Penman, Donald E; Zachos, James C · Proc Natl Acad Sci U S A · 2024

basic_science · Level V

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Abstract

The late Paleocene and early Eocene (LPEE) are characterized by long-term (million years, Myr) global warming and by transient, abrupt (kiloyears, kyr) warming events, termed hyperthermals. Although both have been attributed to greenhouse (CO<sub>2</sub>) forcing, the longer-term trend in climate was likely influenced by additional forcing factors (i.e., tectonics) and the extent to which warming was driven by atmospheric CO<sub>2</sub> remains unclear. Here, we use a suite of new and existing observations from planktic foraminifera collected at Pacific Ocean Drilling Program Sites 1209 and 1210 and inversion of a multiproxy Bayesian hierarchical model to quantify sea surface temperature (SST) and atmospheric CO<sub>2</sub> over a 6-Myr interval. Our reconstructions span the initiation of long-term LPEE warming (~58 Ma), and the two largest Paleogene hyperthermals, the Paleocene-Eocene Thermal Maximum (PETM, ~56 Ma) and Eocene Thermal Maximum 2 (ETM-2, ~54 Ma). Our results show strong coupling between CO<sub>2</sub> and temperature over the long- (LPEE) and short-term (PETM and ETM-2) but differing Pacific climate sensitivities over the two timescales. Combined CO<sub>2</sub> and carbon isotope trends imply the carbon source driving CO<sub>2</sub> increase was likely methanogenic, organic, or mixed for the PETM and organic for ETM-2, whereas a source with higher δ<sup>13</sup>C values (e.g., volcanic degassing) is associated with the long-term LPEE. Reconstructed emissions for the PETM (5,800 Gt C) and ETM-2 (3,800 Gt C) are comparable in mass to future emission scenarios, reinforcing the value of these events as analogs of anthropogenic change.