Topological van der Waals Contact for Two-Dimensional Semiconductors.

Ghods, Soheil; Lee, Hyunjin; Choi, Jun-Hui; Moon, Ji-Yun; Kim, Sein; Kim, Seung-Il; Kwun, Hyung Jun; Josline, Mukkath Joseph et al. · ACS Nano · 2024

basic_science · Level V

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Abstract

The relentless miniaturization inherent in complementary metal-oxide semiconductor technology has created challenges at the interface of two-dimensional (2D) materials and metal electrodes. These challenges, predominantly stemming from metal-induced gap states (MIGS) and Schottky barrier heights (SBHs), critically impede device performance. This work introduces an innovative implementation of damage-free Sb<sub>2</sub>Te<sub>3</sub> topological van der Waals (T-vdW) contacts, representing an ultimate contact electrode for 2D materials. We successfully fabricate p-type and n-type transistors using monolayer and multilayer WSe<sub>2</sub>, achieving ultralow SBH (∼24 meV) and contact resistance (∼0.71 kΩ·μm). Simulations highlight the role of topological surface states in Sb<sub>2</sub>Te<sub>3</sub>, which effectively mitigate the MIGS effect, thereby significantly elevating device efficiency. Our experimental insights revealed the semiohmic behavior of Sb<sub>2</sub>Te<sub>3</sub> T-vdW contacts, with an exceptional photoresponsivity of 716 A/W and rapid response times of approximately 60 μs. The findings presented herein herald topological contacts as a superior alternative to traditional metal contacts, potentially revolutionizing the performance of miniaturized electronic and optoelectronic devices.