Harmonization of rapid triplet up-conversion and singlet radiation enables efficient and stable white OLEDs.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 39277619.
- Also identified by DOI 10.1038/s41467-024-52401-7 and PMC identifier 11401840.
- Licence recorded as CC BY-NC-ND.
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Abstract
White organic light-emitting diodes (WOLEDs) hold significant promise in illumination and displays, but achieving high efficiency while maintaining stability is an ongoing challenge. Here, we strategically combine a blue donor-acceptor thermally activated delayed fluorescence (TADF) emitter featuring rapid reverse intersystem crossing rate and a yellow multi-resonance TADF emitter renowned for the fast radiative transition process to achieve warm WOLEDs with exceptional power efficiency exceeding 190 lm W<sup>-1</sup> and external quantum efficiency (EQE) of 39%, setting records for WOLEDs. Meanwhile, these devices also exhibit an extended operational lifetime (LT<sub>80</sub>) of 446 h at an initial luminance of 1000 cd m<sup>-2</sup>. Another group of blue and yellow emitters based on our strategy achieves a standard white emission and a high EQE of 35.6%, confirming the universality of our strategy. This work presents a versatile strategy to harmonize singlet exciton radiation and triplet exciton up-conversion, thus achieving a win-win situation of efficiency and stability.