A "Two-Pronged" Strategy to Boost Hydrogen Evolution Kinetics on NiFe-Based (Oxy)hydroxides via Oxygen Deficient Ni-Mo-Fe Coordinate Structures for Ultra-Stable Ampere-Level Alkaline Overall Water Splitting.
basic_science · Level V
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- Record sourced from PubMed, PMID 39279569.
- Also identified by DOI 10.1002/adma.202411134.
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Abstract
NiFe (oxy)hydroxides have been regarded as one of the state-of-the-art catalysts for oxygen evolution reaction (OER). Unfortunately, the sluggish hydrogen evolution reaction (HER) kinetics limit its application as bifunctional electrocatalyst for alkaline overall water splitting (OWS). Herein, a "two-pronged" strategy is proposed to construct highly active oxygen deficient Ni-Mo-Fe coordinate structures in NiFe (oxy)hydroxide (NFM-OV<sub>R</sub>/NF), which simultaneously reduces the energy barrier of Volmer and Heyrovsky steps during alkaline HER process and significantly accelerate the reaction kinetics. Consequently, NFM-OV<sub>R</sub>/NF delivers overpotentials as low as 25 and 234 mV to achieve 10 and 1000 mA cm<sup>-2</sup> in 1.0 M KOH, respectively. Furthermore, benefiting from excellent HER and OER activity, NFM-OV<sub>R</sub>/NF exhibits a remarkable OWS activity with cell voltages of 1.44 V and 1.77 V at 10 and 1000 mA cm<sup>-2</sup> in 1.0 M KOH, and displays ultralong-term stability for 600 h at 500 mA cm<sup>-2</sup>, while remaining durable for 300 h in an alkaline water electrolyzer in 30% KOH at 80 °C. The calculated price per gallon of gasoline equivalent for the produced H<sub>2</sub> is $ 0.92, which is much lower than 2026 U.S. Department of Energy target ($ 2.00), demonstrating feasibility and practicability of NFM-OV<sub>R</sub>/NF for industrial applications.