On-Device Pressure-Tunable Moving Schottky Contacts.

Yu, Zhaokuan; Huang, Xuanyu; Bian, Jinbo; He, Yuqing; Lu, Xin; Zheng, Quanshui; Xu, Zhiping · Nano Lett · 2024

basic_science · Level V

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Abstract

Contact engineering enhances electronic device performance and functions but often involves costly, inconvenient fabrication and material replacement processes. We develop an <i>in situ</i>, reversible, full-device-scale approach to reconfigurable 2D van der Waals contacts. Ideal p-type Schottky contacts free from surface dangling bonds and Fermi-level pinning are constructed at structurally superlubric graphite-MoS<sub>2</sub> interfaces. Pressure control is introduced, beyond a threshold of which tunneling across the contact can be activated and amplified at higher loads. Record-high figures of merits such an ideality factor nearing 1 and an off-state current of 10<sup>-11</sup> A were reported. The concept of on-device moving contacts is demonstrated through a wearless Schottky generator, operating with an optimized overall efficiency of 50% in converting weak, random external stimuli into electricity. The device combines generator and pressure-sensor functions, achieving a high current density of 31 A/m<sup>2</sup> and withstanding over 120,000 cycles, making it ideal for neuromorphic computing and mechanosensing applications.