Emerging Opportunities of Colloidal Quantum Dots for Photocatalytic Organic Transformations.

Abstract

Colloidal quantum dots (QDs) have emerged as a versatile photocatalyst for a wide range of photocatalytic transformations owing to its high absorption coefficient, large surface-to-volume ratio, high stability, and efficient charge and energy transfer dynamics. The past decades have witnessed a rapid development of QDs for artificial photocatalysis. In this review, the unique characteristics of QDs are focused on, including quantum size effect, compositional and structural diversity, tunable surface chemistry, and photophysics, that can be utilized for photocatalytic transformations. The recent advancements in photocatalytic organic transformations enabled by QDs photocatalysts are summarized. The unique opportunities of QDs are highlighted to tackle organic reactions that are previously unattainable with small molecule photocatalysts. Lastly, an outlook is provided for future directions in this field.