Tailoring Ultra-Narrowband Tetraborylated Multiple Resonance Emitter for High-Performance Blue OLED.
basic_science · Level V
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- Record sourced from PubMed, PMID 39385644.
- Also identified by DOI 10.1002/adma.202410096.
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Abstract
Ultra-narrowband multiple resonance (MR) emitters are a key component in the fabrication of highly efficient and stable blue organic light-emitting diodes (OLEDs). To explore the theoretical boundaries of wavelength and full width at half maximum (FWHM) in blue emitters, the currently narrowest boron-based MR emitter is carefully designed by integrating the superior v-DABNA and BBCz-DB structures under the auspices of the ingenious short-range charge-transfer region regulation strategy. The target tetraboron compound TB-PB demonstrates a blue emission with an emission maximum of 473 nm, a small FWHM of 12 nm and a CIEy coordinate of 0.14. Benefiting from the emitter's high photoluminescence quantum yield (99%), low excited-state energy (2.74 eV) and short delayed fluorescence lifetime (0.53 µs), the corresponding OLED achieves exceptional efficiencies of 36.4%, 49.1 cd A<sup>-1</sup>, and 51.4 lm W<sup>-1</sup> with a record-high luminescence of 9.0 × 10<sup>5</sup> cd m<sup>-2</sup>, an ultra-narrow FWHM of 15 nm and a CIEy coordinate of 0.20. These breakthroughs will accelerate the development of next-generation blue emitters and lead to the advancement of OLED technology.