Room-Temperature Ferromagnetism with Strong Spin-Orbit Coupling Achieved in CaRuO₃ Interfacial Phase via Magnetic Proximity Effect.

Abstract

Recently, theoretical and experimental research predicted that ferromagnets with strong spin-orbit coupling (SOC) could serve as spin sources with dramatically enhanced spin-orbit torque (SOT) efficiency due to the combination of spin Hall effect and anomalous Hall effect (AHE), presenting potential advantages over conventional nonmagnetic heavy metals. However, materials with a strong SOC and room-temperature ferromagnetism are rare. Here, we report on a ferromagnetic (FM) interfacial phase with Curie temperature exceeding 300 K in the heavy transition-metal oxide CaRuO₃, in proximity to La_0.67Sr_0.33MnO₃. Electron energy loss and polarized neutron reflectometry spectra reveal the strong charge transfer from Ru to Mn at the interface, triggering antiferromagnetic exchange interactions between interfacial Ru/Mn ions and thus transferring magnetic order from La_0.67Sr_0.33MnO₃ to CaRuO₃. An obvious advantage of such interfacial phase is the enhanced anomalous Hall effect at temperatures from 150 to 300 K. Compared to the most promising room-temperature ferromagnetic oxide La_0.67Sr_0.33MnO₃, the anomalous Hall conductivity σ_<i>xy</i>^AHE (or anomalous Hall angle θ_H) of CaRuO₃/La_0.67Sr_0.33MnO₃ superlattices is increased by 30 (or 31) times at 150 K and 10 (or 3) times at 300 K. This work demonstrates a special approach for inducing ferromagnetism in heavy transition-metal oxides with strong SOC, offering promising prospects for all-oxide-based spintronic applications.