Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization.
basic_science · Level V
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- Record sourced from PubMed, PMID 39641200.
- Also identified by DOI 10.1002/adma.202412678.
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Abstract
Beyond the crystalline photodiodes for infrared visualization, with the limitation of opacity and complex lithographic processes, organic upconversion device (UCD) have emerged as a potential alternative. In this research, a ternary compensation strategy is implemented in a non-fullerene-based active layer to reduce the dark current of the detector and enhance its detection performance, which enables high-sensitive efficient upconversion device for near-infrared light (NIR) visualization. The device achieves an infrared-to-visible upconversion efficiency of 16.68% when resolving the 980 nm infrared signal at a power density of 0.4 mW cm<sup>-2</sup>. In addition, by replacing the semitransparent matrix electrodes, a large-area (12.25 cm<sup>2</sup>) is further fabricated, lightweight (6.5 g containing encapsulation), pixel-less (equivalent resolution 1270 ppi), and semitransparent (AVT ≈40%) UCD with microsecond response time. The fabricated UCD is demonstrated in pixel-less active infrared naked-eye visualization and infrared counter-surveillance, fostering the advancement of infrared visualization technology.