Efficient Spin-Light-Emitting Diodes With Tunable Red to Near-Infrared Emission at Room Temperature.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 39887568.
- Also identified by DOI 10.1002/adma.202413669 and PMC identifier 11899487.
- Licence recorded as CC BY-NC.
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Abstract
Spin light-emitting diodes (spin-LEDs) are important for spin-based electronic circuits as they convert the carrier spin information to optical polarization. Recently, chiral-induced spin selectivity (CISS) has emerged as a new paradigm to enable spin-LED as it does not require any magnetic components and operates at room temperature. However, CISS-enabled spin-LED with tunable wavelengths ranging from red to near-infrared (NIR) has yet to be demonstrated. Here, chiral quasi-2D perovskites are developed to fabricate efficient spin-LEDs with tunable wavelengths from red to NIR region by tuning the halide composition. The optimized chiral perovskite films exhibit efficient circularly polarized luminescence from 675 to 788 nm, with a photoluminescence quantum yield (PLQY) exceeding 86% and a dissymmetry factor (g<sub>lum</sub>) ranging from 8.5 × 10<sup>-3</sup> to 2.6 × 10<sup>-2</sup>. More importantly, direct circularly polarized electroluminescence (CPEL) is achieved at room temperature in spin-LEDs. This work demonstrated efficient red and NIR spin-LEDs with the highest external quantum efficiency (EQE) reaching 12.4% and the electroluminescence (EL) dissymmetry factors (g<sub>EL</sub>) ranging from 3.7 × 10<sup>-3</sup> to 1.48 × 10<sup>-2</sup> at room temperature. The composition-dependent CPEL performance is further attributed to the prolonged spin lifetime as revealed by ultrafast transient absorption spectroscopy.