Supramolecular Chemistry in Metal-Organic Framework Materials.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 39895182.
- Also identified by DOI 10.1002/adma.202414509 and PMC identifier 12747472.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Far from being simply rigid, benign architectures, metal-organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically-interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal-organic frameworks emerge as important directions for the field.