Negative-Valent Platinum Stabilized by Pt─Ni Electron Bridges on Oxygen-Deficient NiFe-LDH for Enhanced Electrocatalytic Hydrogen Evolution.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 40040319.
- Also identified by DOI 10.1002/adma.202500595.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
The unique hydrogen adsorption characteristics of negatively charged platinum play a crucial role in enhancing the electrocatalytic hydrogen evolution reaction. However, atomically dispersed Pt atoms are typically anchored to the support through non-metallic atom bonds, resulting in a high oxidation state. Here, atomically dispersed Pt atoms are anchored in oxygen-deficient NiFe-LDH. Electron transfer between Pt and NiFe-LDH occurs primarily through Pt─Ni bonds rather than the conventional Pt─O bonds. Oxygen vacancies in the NiFe-LDH promote additional electron transfer from Ni to Pt, thereby reducing the valence state of Pt and enhancing hydrogen adsorption. Meanwhile, the elevated valence state of Ni increases the catalyst's hydrophilicity and reduces the energy barrier for hydrolysis dissociation. This catalyst demonstrates remarkably low overpotentials of 4 and 9 mV at 10 mA cm<sup>-2</sup> in 1 m KOH and 1 m KPi, respectively. Additionally, its mass activity is 51.5 and 23.7 times higher that of Pt/C, respectively. This study presents a novel strategy for enhancing electrocatalytic performance through the rational design of coordination environments and electronic structures in supported metal catalysts.