Intertwined Topological Phases in TaAs<sub>2</sub> Nanowires with Giant Magnetoresistance and Quantum Coherent Surface Transport.

Roy, Anand; Eyal, Anna; Majlin Skiff, Roni; Barick, Barun; Escribano, Samuel D; Brontvein, Olga; Rechav, Katya; Bitton, Ora et al. · Adv Mater · 2025

basic_science · Level V

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Abstract

Nanowires (NWs) of topological materials are emerging as an exciting platform to probe and engineer new quantum phenomena that are hard to access in bulk phase. Their quasi-1D geometry and large surface-to-bulk ratio unlock new expressions of topology and highlight surface states. TaAs<sub>2</sub>, a compensated semimetal, is a topologically rich material harboring nodal-line, weak topological insulator (WTI), C<sub>2</sub>-protected topological crystalline insulator, and Zeeman field-induced Weyl semimetal phases. We report the synthesis of TaAs<sub>2</sub> NWs in situ encapsulated in a dielectric SiO<sub>2</sub> shell, which enable to probe rich magnetotransport phenomena, including metal-to-insulator transition and strong signatures of topologically nontrivial transport at remarkably high temperatures, direction-dependent giant positive, and negative magnetoresistance, and a double pattern of Aharonov-Bohm oscillations, demonstrating coherent surface transport consistent with the two Dirac cones of a WTI surface. The SiO<sub>2</sub>-encapsulated TaAs<sub>2</sub> NWs show room-temperature conductivity up to 15 times higher than bulk TaAs<sub>2</sub>. The coexistence and susceptibility of topological phases to external stimuli have potential applications in spintronics and nanoscale quantum technology.