Mitigating Surface Energy and Core-Shell Interface Strain of Yb³⁺-Doped ZnSe-Based Quantum Dots for Pure-Blue Emission QLED Devices.

Abstract

Large ZnSe quantum dots (QDs) with an emission peak ≈450 nm hold significant promise for display technologies. However, achieving efficient pure-blue emission through the enlargement of ZnSe nanocrystals remains a significant challenge. In this study, a breakthrough is reported in growing large-size ZnSe QDs well beyond the exciton Bohr radius through Yb³⁺ doping strategy. Yb³⁺ doping reduces the surface energy of the ZnSe (220) crystal plane and alleviates interface strain in the ZnSe/ZnS structure, enabling the QDs to grow larger while maintaining enhanced crystal stability. The resulting Yb: ZnSe/ZnS QDs exhibit pure-blue emission at 453 nm, with a full width at half maximum (FWHM) of 46 nm and a high photoluminescence quantum yield (PLQY) of 67.5%. When integrated into quantum dot light-emitting diodes (QLEDs), the devices display electroluminescence (EL) at 455 nm, with an external quantum efficiency (EQE) of 1.35%, and a maximum luminance of 1337.08 cd m^-2.