Mechanism of client loading from BiP to Grp94 and its disruption by select inhibitors.

Azam, Tara P; Han, Jiaqi; Deans, Erin E; Huang, Bin; Hoxie, Reyal; Friedman, Larry J; Gelles, Jeff; Street, Timothy O · Nat Commun · 2025

basic_science · Level V

Where this comes from

Abstract

Hsp90 chaperones are a long-standing cancer drug target with numerous ATP-competitive inhibitors in clinical trials. Client proteins are transferred from Hsp70 to Hsp90 in a stepwise process of client delivery, loading, and trapping, but little is known about how inhibitors influence these steps. By examining the ER-resident BiP/Grp94 system (Hsp70/Hsp90 paralogs), we discover that some inhibitors allow BiP to push Grp94 into the client loading conformation, whereas other inhibitors block this conformational change and destabilize a BiP/client/Grp94 ternary complex. We uncover how BiP drives Grp94 into the client loading state and identify a structural explanation for why only a select group of inhibitors disrupt client loading on Grp94. These results show a client loading mechanism with specific shared features between the Hsp70/Hsp90 systems in the ER and cytosol and open a new avenue for rational Hsp90 drug design.

Medical subject headings