Conservative dielectric functions and electrical conductivities from the multicomponent Bhatnagar-Gross-Krook equation.

Abstract

A considerable number of semiempirical and first-principles models have been created to describe the dynamic response of a collisionally damped charged-particle system. However, known challenges persist for established dynamic structure factors (DSFs), dielectric functions, and conductivities. For instance, the semiempirical Drude-Smith conductivity [Smith, Phys. Rev. B 64, 155106 (2001)0163-182910.1103/PhysRevB.64.155106] lacks interpretability, and the first-principles Mermin dielectric function [Mermin, Phys. Rev. B 1, 2362 (1970)0556-280510.1103/PhysRevB.1.2362] does not satisfy the frequency sum rule [Atwal and Ashcroft, Phys. Rev. B 65, 115109 (2002)0163-182910.1103/PhysRevB.65.115109]. In this work, starting from the multicomponent Bhatnagar-Gross-Krook (BGK) kinetic equation, we produce a multispecies susceptibility that conserves number and momentum, which we refer to as the completed Mermin susceptibility, and we explore its properties and uses. We show that the completed Mermin susceptibility satisfies the frequency sum (f-sum) rule. We compute the associated DSF and find that momentum conservation qualitatively impacts the DSF's shape for a carbon-contaminated deuterium and tritium plasma under NIF hot-spot conditions. In the Appendixes, we provide numerical implementations of the completed Mermin susceptibility, for the reader's convenience. Further, we produce a non-Drude conductivity model, by taking the single-species limit and introducing free parameters in the terms that enforce number and momentum conservation. To illustrate how number and momentum conservation impact the dynamical conductivity shape, we apply our conductivity model to dynamical gold conductivity measurements [Chen et al., Nature Commun. 12, 1638 (2021)2041-172310.1038/s41467-021-21756-6]. Finally, comparing our model to the Drude-Smith conductivity model, we conclude that Smith's phenomenological parameter violates local number conservation.