Surface Tension-Driven Self-Planarization of MXene Liquid Crystalline Fiber for High-Performance Energy Storage.
basic_science · Level V
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- Record sourced from PubMed, PMID 40249073.
- Also identified by DOI 10.1021/acsnano.5c03111.
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Abstract
2D MXene-based liquid crystalline (LC) systems have emerged as promising precursors for constructing highly ordered functional materials, such as fibers, films, and aerogels via solution-based processing. In this study, we demonstrate surface tension-mediated self-planarization of MXene LC fibers by adjusting the solvent composition during wet-spinning, targeting improved electrochemical performance. Ethanol, a poor solvent for MXene, induced spontaneous parallel alignment of MXene platelets and facilitated densification into a ribbon-like geometry during coagulation. The resulting fibers featured a pore volume of 0.11 cm<sup>3</sup> g<sup>-1</sup> and an average pore diameter of 34 nm, enabling a volumetric capacitance of 1721.7 F cm<sup>-3</sup> and an electrical conductivity of 9211.66 S cm<sup>-1</sup>. The mechanism underlying the self-planarization was investigated by using a range of solvents with varying physicochemical properties to identify key processing parameters. The MXene fibers were successfully implemented into LED-powered supercapacitor prototypes, demonstrating potential applicability for wearable energy applications.