Large low-field-driven electrocaloric effect in organic-inorganic hybrid TMCM-CdCl<sub>3</sub>.
basic_science · Level V
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- Record sourced from PubMed, PMID 40301308.
- Also identified by DOI 10.1038/s41467-025-58914-z and PMC identifier 12041295.
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Abstract
Due to environmental-friendliness and high-efficiency, electrocaloric effect (ECE) is widely regarded as a refrigeration technology for tomorrow. Herein, utilizing organic-inorganic hybridization strategy, we achieve the largest low-field-driven ECE and highest directly-measured electrocaloric strength (ECS) via packing sphere-like organic cation (CH<sub>3</sub>)<sub>3</sub>NCH<sub>2</sub>Cl<sup>+</sup> (TMCM<sup>+</sup>) into inorganic one-dimension (1-D) CdCl<sub>3</sub> chain framework. Single-crystal X-ray (SC-XRD) diffraction combined with Raman Spectra reveals that the simultaneous order-disorder transition of organic cations and dramatic structure change of inorganic framework are responsible for the large ECE. Moreover, the measured P-E loops and density function theory (DFT) calculations convey that the distinctive electric-field-induced metastable phase and consequential two-step meta-electric transition could lower the transition energy barrier and account for the low driving field. This work shows that the low-symmetry interaction between inorganic framework and organic cations plays a key role in achieving large ECE under low-field, which provides a method for designing high-performance electrocaloric materials via organic-inorganic hybridization.