Post-oxidation of all-organic electrocatalysts to promote O-O coupling in water oxidation.

He, Chun-Ting; Yu, Li-Hong; Liu, Haiming; Wang, Qing; Ye, Zi-Ming; Zhang, Jia; Wang, Li-Dong; He, Mei-Qian et al. · Nat Commun · 2025

basic_science · Level V

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Abstract

Covalently bonded metal-free electrocatalysts exhibit significant potential for sustainable energy technologies, yet their performances remain unsatisfactory compared with metal-based catalysts. Herein, we propose an all-organic electrocatalyst, MEC-2, that conforms to the infrequent oxide path mechanism in alkaline oxygen evolution reaction through post-oxidation modification. MEC-2 achieves an intrinsic overpotential of 257.7 ± 0.6 mV at 10 mA·cm<sup>-2</sup> and possesses durability with negligible degradation over 100,000 CV cycles or 250 h of operation at 1.0 A·cm<sup>-2</sup>, being comparable to the advanced metal-based OER electrocatalysts. The <sup>18</sup>O-labeled operando characterization and theoretical calculations unveil that post-oxidation modification enhances the electron affinity to OH intermediates, and adjusts the adsorption configuration and proximity distance of O intermediates, thereby promoting direct O-O radical coupling. In this work, we show a fresh perspective for understanding the role of non-metallic elements/functional groups in electrocatalysis, and to a certain extent, narrows the gap between all-organic electrocatalysts and metal-based electrocatalysts.