Coarsening in bent-core liquid crystals: a molecular dynamics study.

Birdi, Nishant; Wilding, Nigel B; Puri, Sanjay; Banerjee, Varsha · Soft Matter · 2025

basic_science · Level V

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Abstract

We use molecular dynamics simulations to study coarsening dynamics in achiral banana-shaped bent-core liquid crystals following a quench from the high concentration polar smectic (SmX) phase to lower concentrations that favor the exotic twist-bend (TB) phase. Our novel result is the identification of an intermediate splay-bend state emerging prior to the eventual TB phase. The latter coarsens <i>via</i> the annihilation of beta lines which are analogous to string defects in nematic liquid crystals. Our findings are relevant for a large class of chiral systems assembled from achiral entities.