Degradation Pathway Tailoring through Nanocrystal Interface Engineering for Photostable Perovskite Solar Cells.
basic_science · Level V
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- Record sourced from PubMed, PMID 40424534.
- Also identified by DOI 10.1021/acs.nanolett.5c01111.
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Abstract
While organic-inorganic hybrid perovskites (ABX<sub>3</sub>) hold immense photovoltaic potential, operational instability originating from defect-mediated ion migration and light-induced degradation remains a critical bottleneck. Here, we adopt Cs<sub>2</sub>PbI<sub>2</sub>Cl<sub>2</sub> nanocrystals (CPIC-NCs) and CsPbCl<sub>3</sub> nanocrystals (CPC-NCs) to modify the interface of the perovskite light-absorbing layer. Beyond conventional defect-healing roles (Cs<sup>+</sup>/halide filling of the A/X-site vacancies), this modification can fundamentally alter the degradation pathways of perovskite films under light exposure. Our study reveals CPIC-NCs serve as a superior modifier by inducing a more controllable formation of Pb(OH)I and effectively suppressing the decomposition of perovskite into lead iodide after long-term light aging. Following the CPIC-NCs modification of the solar cells, a champion power conversion efficiency of 24.28% was achieved. Moreover, the unencapsulated devices retained over 90% of their initial efficiency after 600 h under ISOS-L-1I and 4500 h under ISOS-D-1 conditions. This work establishes nanocrystal-mediated interface control as a dual-defect/degradation regulatory strategy for perovskite optoelectronics.