Finding a Novel Borate Ferroelectric with Random Domain Structures for Deep-UV Quasi-Phase-Matching.
basic_science · Level V
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- Record sourced from PubMed, PMID 40444403.
- Also identified by DOI 10.1002/adma.202505930.
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Abstract
Finding competitive nonlinear optical (NLO) crystals for practical deep-ultraviolet (deep-UV) lasers remains a fundamental yet challenging goal in photonic materials research. The production of deep-UV lasers through the mesoscopic domain structure of ferroelectric materials has been a popular research area via quasi-phase-matching (QPM). However, as of right present, no ferroelectric in the deep-UV area is able to provide QPM laser output. Here, a new room-temperature borate ferroelectric Ba<sub>3</sub>Mg<sub>3</sub>(BO<sub>3</sub>)<sub>3</sub>F<sub>3</sub> (BMBF) is presented. The ferroelectricity of BMBF crystals exhibits significant relaxor behavior and the random domain structure can relax the strict phase-matching conditions, rendering it a disordered NLO medium. Benefiting from its unique ferroelectric properties, BMBF crystal achieves a second-harmonic generation output energy of 3.55 µJ for 398 to 199 nm wavelength frequency conversion, even in the absence of birefringent phase-matching conditions. This result demonstrates that BMBF is a promising candidate for deep-UV QPM applications. Furthermore, this study expands the frontiers of borate ferroelectrics while the realization of deep-UV light output using BMBF crystal motivates and provides a path for its broader application.