Gate-Tunable Band Edge in Few-Layer MoS<sub>2</sub>.

Masseroni, Michele; Soltero, Isaac; McHugh, James G; Rozhansky, Igor; Li, Xue; Schmidhuber, Alexander; Niese, Markus; Taniguchi, Takashi et al. · Nano Lett · 2025

basic_science · Level V

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Abstract

Transition metal dichalcogenides (TMDs) have garnered significant research interest due to the variation in band edge locations within the hexagonal Brillouin zone between single-layer and bulk configurations. In monolayers, the conduction band minima are centered at the <i>K</i> points, whereas in multilayers, they shift to the <i>Q</i> points, midway between the Γ and <i>K</i> points. In this study, we conduct magnetotransport experiments to measure the occupation in the <i>Q</i> and <i>K</i> valleys in four-layer molybdenum disulfide (MoS<sub>2</sub>). We demonstrate electrostatic tunability of the conduction band edge by combining our experimental results with a hybrid <i>k</i>·<i>p</i> tight-binding model that accounts for interlayer screening effects in a self-consistent manner. Furthermore, we extend our model to bilayer and trilayer MoS<sub>2</sub>, reconciling prior experimental results and quantifying the tunable range of band edges in atomically thin TMDs.