Stable and uniform self-assembled organic diradical molecules for perovskite photovoltaics.
basic_science · Level V
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- Record sourced from PubMed, PMID 40570056.
- Also identified by DOI 10.1126/science.adv4551.
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Abstract
Organic self-assembled molecules (SAMs), which are widely used in perovskite solar cells (PSCs), should exhibit enhanced performance to support the ongoing advancement of perovskite photovoltaics. We designed diradical SAMs through a coplanar conjugation of a donor-acceptor strategy to facilitate hole transport across the SAMs. The diradical SAMs exhibited high photothermal and electrochemical stability as well as improved assembly uniformity and large-area solution processability attributed to molecular steric hindrance design. We used an advanced scanning electrochemical cell microscopy-thin-layer cyclic voltammetry technique to accurately determine the carrier transfer rate, stability, and assembly properties of the SAMs. Ultimately, the efficiencies of the PSCs exceeded 26.3%, minimodules (10.05 cm<sup>2</sup>) reached 23.6%, and perovskite-silicon tandem devices (1 cm<sup>2</sup>) surpassed 34.2%. The PSCs maintained >97% after 2000 hours tracking at 45°C.