Nicotinamide Solid Cosolvent Enhanced Two-Electron Zinc Peroxide Chemistry for Stable Neutral Zinc-Air Batteries.
basic_science · Level V
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- Record sourced from PubMed, PMID 40583254.
- Also identified by DOI 10.1021/acs.nanolett.5c01562.
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Abstract
Zinc-air batteries (ZABs) are promising energy storage systems due to their high energy density and sustainability. Neutral electrolytes effectively address the CO<sub>2</sub> sensitivity and zinc corrosion issues in alkaline systems but face challenges such as hydrogen evolution reactions (HER) and sluggish oxygen reduction and evolution reactions (ORR/OER) dynamics. Herein, we introduce nicotinamide (NAM), a solid cosolvent with high donor number (DN) and acceptor number (AN) in neutral electrolyte. Due to its high DN, NAM readily coordinates with Zn<sup>2+</sup> to weaken H<sub>2</sub>O's dominance in the primary solvation sheath, reducing the required zinc salt concentration. NAM's strong hydrogen bonding with H<sub>2</sub>O limits water mobility, suppressing HER and zinc corrosion. Its high AN enhances O<sub>2</sub><sup>-</sup> affinity, enabling efficient two-electron zinc peroxide (ZnO<sub>2</sub>) chemistry. These advancements lead to remarkable stability, including nearly 2000 h in symmetric cells and 560 h in ZABs. Our electrolyte design highlights the potential of advancing neutral ZAB technology.