Plume-induced emissions of deep methane linked to the end-Guadalupian mass extinction.

Liu, Sheng-Ao; Xiong, Zhili; Wu, Tianhao; Zhao, Mingyu · Nat Commun · 2025

basic_science · Level V

Where this comes from

Abstract

Methane (CH<sub>4</sub>) is a potent greenhouse gas, and massive CH<sub>4</sub> emissions have the capacity to cause rapid and catastrophic climate effects. Here we report findings of large amounts of CH<sub>4</sub> occurring as an important vapor phase in melt inclusions trapped by magmas in the plume-related Permian Emeishan large igneous province (LIP). Lines of evidence indicate that the CH<sub>4</sub> is dominantly abiogenic and primarily had a mantle origin. Undegassed magmas are estimated to contain ~ 0.03% (by weight) CH<sub>4</sub>, which coincides with the relatively low oxygen fugacities of primary Emeishan LIP magmas. Our findings demonstrate that abiogenic CH<sub>4</sub> can be generated in the mantle sources of a plume-related LIP, and that such CH<sub>4</sub> could be brought into the surface by LIP magmatism and lead to strong warming. Quantitative models suggest that release of magmatic CH<sub>4</sub> in the Emeishan LIP (7.4 × 10<sup>3</sup> Gt) had a significant contribution to the end-Guadalupian mass extinction.