Strategic energy-level modulation in porous heterojunctions: advancing gas sensing through Type-I to Type-II transitions.
basic_science · Level V
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- Record sourced from PubMed, PMID 40681497.
- Also identified by DOI 10.1038/s41467-025-61836-5 and PMC identifier 12274526.
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Abstract
To significantly enhance reaction efficiency of porous heterojunctions in various applications, precise engineering of customization heterostructures through energy-level modulation is indispensable. Herein, the preparation of a core-shell porous heterojunction, UiO-66@TDCOF, is reported. Taking advantage of adjustable structure of metal-organic frameworks (MOFs), the energy-level of UiO-66 core is tailored to precisely align with that of porphyrin-based covalent organic framework (denoted as TDCOF) shell. As a results, the heterojunction transitions flexibly from a type-I to a type-II configuration, which remarkably enhances the efficiency of charge separation under light irradiation, resulting in exceptional performances in chemiresistive gas sensing. Notably, the sensitivity of (NH<sub>2</sub>)<sub>1.24</sub>-UiO-66@TDCOF towards NO<sub>2</sub> is at a high level among all reported heterojunctions under visible-light condition, surpassing the majority of previously reported MOF and COF materials. This research not only presents a strategy for the design of heterojunctions but also gives an approach to material design tailored for chemical applications.