On a Continuous Aqueous Thermogalvanic Redox Agent with Anomalous Thermopower.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 40705735.
- Also identified by DOI 10.1021/acs.nanolett.5c02774 and PMC identifier 12333407.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Achieving stable and sustained power output remains a major challenge in the development of ionic thermoelectric devices (such as thermogalvanic cells and thermoionic capacitors) for low-grade heat harvesting. Many such systems exhibit strong performance in the initial throes of operation but degrade rapidly over time, limiting their utility. Here, we report an aqueous thermogalvanic redox agent ([Ni(bpy)<sub>3</sub>]<sup>2+/3+</sup>) with a Seebeck coefficient approximately double that of the canonical [Fe(CN)<sub>6</sub>]<sup>4-/3-</sup>, which can be utilized continuously for multiple hours under large temperature gradients (Δ<i>T</i> ≥ 60 K) without significant change in electrical performance. Molecular dynamics simulations suggest that significant differences in hydration shell behavior between the oxidant and reductant, which in turn provide a significant (here configurational) entropy difference, drive the observed thermopower. This new redox pair demonstrates stability, cyclability, and tunability in both liquid- and gel-based electrolytes, and provides a novel redox platform from which to build next-generation high-thermopower waste-heat recovery cells.