Practical Considerations in the Design and Use of Non-Crystalline Metal-Organic Frameworks.

Mahdavi, Hamidreza; Zadehahmadi, Farnaz; Arzani, Mehran; Melag, Leena; Sutton, Ashley L; Sadiq, Muhammad M; Xie, Zongli; Hill, Matthew R et al. · Adv Mater · 2025

review · Level V

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Abstract

The concept of non-Crystalline Metal-Organic Frameworks (MOFs) is both theoretically exciting and rich in potential applications. Since their conceptual introduction, research in this field has experienced significant growth. This review provides a comprehensive overview of the design, synthesis, and applications of non-crystalline MOFs, highlighting the current state of the art. It examines the fundamental principles of non-crystalline MOFs, the various synthetic approaches, and the nature of non-crystalline MOFs. Additionally, the review outlines their pathway from the laboratory to industrial applications, emphasizing challenges and opportunities for further development.