Dual-Strategy Direct Photocatalytic Patterning for Efficient Perovskite Nanocrystal LED Displays.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 40741783.
- Also identified by DOI 10.1002/adma.202508217 and PMC identifier 12548516.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Achieving nondestructive, high-resolution patterning of perovskite nanocrystals (PeNCs) is essential for next-generation near-eye displays. However, the intrinsic instability of PeNCs renders conventional patterning methods detrimental to their optical and electrical properties. Herein, a dual strategy is reported that enables both high-resolution patterning and the fabrication of efficient light-emitting diodes (LEDs). The first strategy involves an advanced direct photocatalytic patterning method. Thiol crosslinkers are systematically investigated and identified 1,8-octanedithiol and 1,10-decanedithiol as optimal candidates due to their solvent compatibility, colloidal stability, and ability to achieve nondestructive patterning with high resolution and fidelity. The second strategy introduces a film-state ligand exchange (FLE) process to enhance the optical and electrical properties of patterned PeNC films. Replacing long-chain ligands with short-chain ammonium halides results in denser surface passivation and enhanced charge transport capability. Dual strategy enabled high-performance crosslinked PeNC-LEDs, including a maximum external quantum efficiency of 14.7% and luminance of ≈25,400 cd m<sup>-2</sup> for green CsPbBr<sub>3</sub> LEDs, representing the highest values reported for green CsPbBr<sub>3</sub> PeNC-LEDs obtained via direct optical patterning. Furthermore, FLE enabled post-patterning halide exchange, representing the first demonstration of a red crosslinked CsPbBr<sub>x</sub>I<sub>3-x</sub> PeNC-LED via direct optical patterning. This study establishes molecular and lithographic design principles for integrating colloidal nanocrystals into next-generation displays and optoelectronics.