Gas Dynamically Confined Synthesis of Platinum-Based Intermetallic Nanowires for Active and Ultrastable Oxygen Reduction Catalysis.
basic_science · Level V
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- Record sourced from PubMed, PMID 40834390.
- Also identified by DOI 10.1021/acsnano.5c10292.
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Abstract
Precisely controlling the surface and internal atomic structures of platinum (Pt)-based nanocrystals remains a critical challenge for developing high-performance oxygen reduction reaction (ORR) catalysts. Here, we report a gas dynamically confined strategy leveraging hydrogen adsorption to synthesize Pt-based intermetallic nanowires (NWs) with ordered bulk atomic lattices (Pt<sub>3</sub>Fe L1<sub>2</sub>, Pt<sub>3</sub>Co L1<sub>2</sub>, PtNi L1<sub>0</sub>) and abundant high-index {311}, {211}, and {221} facets. Dynamic hydrogen adsorption reduces surface energy and suppresses atomic migration during high-temperature annealing, preserving the one-dimensional morphology and enabling structural ordering, as confirmed by in situ transmission electron microscopy and density functional theory calculations. The resultant ordered Pt<sub>3</sub>Fe NWs exhibit a mass activity of 0.98 A mg<sub>Pt</sub><sup>-1</sup> and ultrahigh stability, retaining 93.9% of mass activity after 30,000 cycles and 86.4% of power density after 70,000 cycles. The synergistic effects of ordered atomic arrangements, high-index facets, and one-dimensional geometry optimize electronic properties and active-site energetics, enhancing both activity and stability. This strategy of designing structurally precise Pt-based intermetallic catalysts demonstrates a potential for application in fuel cell technologies.