Deterministic Formation of Single Organic Color Centers in Single-Walled Carbon Nanotubes.

Kozawa, Daichi; Shiota, Yuto; Wang, Mengyue; Kato, Yuichiro K · Nano Lett · 2025

basic_science · Level V

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Abstract

Quantum light sources using single-walled carbon nanotubes show promise for quantum technologies but face challenges in achieving precise control over color center formation. Here, we present a novel technique for deterministic creation of single organic color centers in carbon nanotubes using <i>in situ</i> photochemical reaction. By monitoring discrete intensity changes in photoluminescence spectra, we achieve precise control over the formation of individual color centers. Furthermore, our method allows for position-controlled formation of color centers as validated through photoluminescence imaging. We also demonstrate photon antibunching from a color center, confirming the quantum nature of the defects formed. This technique represents a significant step forward in the precise engineering of atomically defined quantum emitters in carbon nanotubes, facilitating their integration into advanced quantum photonic devices and systems.