<i>d</i>-Wave Polarization-Spin Locking in Two-Dimensional Altermagnets.

Liu, Zhao; Medhekar, Nikhil V · Nano Lett · 2025

basic_science · Level V

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Abstract

We report the emergence of an uncharted phenomenon, termed <i>d</i>-wave polarization-spin locking (PSL), in two-dimensional (2D) altermagnets. This phenomenon arises from nontrivial Berry connections, resulting in perpendicular electronic polarizations in the spin-up and spin-down channels. Symmetry-protected <i>d</i>-wave PSL occurs exclusively in <i>d</i>-wave altermagnets with tetragonal layer groups. To identify 2D altermagnets capable of exhibiting this phenomenon, we propose a symmetry-eigenvalue-based criterion and a rapid method by observing the spin-momentum locking. Using first-principles calculations, monolayer Cr<sub>2</sub>X<sub>2</sub>O (X = Se, Te) characterizes promising candidates for <i>d</i>-wave PSL, driven by the unusual charge order in these monolayers. This unique polarization-spin interplay leads to spin-up and spin-down electrons accumulating at orthogonal edges, enabling potential applications as spin filters or splitters in spintronics. Furthermore, <i>d</i>-wave PSL introduces an unexpected spin-driven ferroelectricity in conventional antiferromagnets. Such magnetoelectric coupling positions the <i>d</i>-wave PSL as an ideal platform for fast antiferromagnetic memory devices.