Chiral Plasmonic Nanocavities Enable Efficient Circularly Polarized Luminescence through Tailored Optical Chirality.
basic_science · Level V
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- Record sourced from PubMed, PMID 40983873.
- Also identified by DOI 10.1021/acsnano.5c05909.
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Abstract
Ultrastrong enhancement of circularly polarized luminescence (CPL) is achieved with chiral plasmonic nanocavities made of helicoid-on-mirror structures. The large local optical chirality enhancement, along with local electric field enhancement in the ultrathin chiral nanocavities, generates prominent chiral photoluminescence with a dissymmetric factor (<i>g</i><sub>lum</sub>) of up to ∼0.6 and a quantum yield (QY) of ∼29%. Such a large chiroptic enhancement is correlated to the morphology of the helicoids, where the sharp corners strongly enhance the local E-field (∼500) and optical chirality (∼90). This chiral plasmonic nanocavity can also be applied to enhance the CPL of a chiral dye (R/S-1) with an emission band off the plasmon resonance, which leads to a 4-fold enhancement of its <i>g</i><sub>lum</sub> (∼0.2) and QY up to ∼60%. This superior enhancement strategy not only demonstrates the synergistic enhancement of both QY and <i>g</i><sub>lum</sub> but also provides a promising route toward superior CPL devices for practical applications.