Late-stage direct double borylation of B/N-based multi-resonance framework enables high-performance ultra-narrowband deep-blue organic light-emitting diodes.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41053193.
- Also identified by DOI 10.1038/s41467-025-63908-y and PMC identifier 12501214.
- Licence recorded as CC BY-NC-ND.
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Abstract
Multi-resonance thermally activated delayed fluorescence (MR-TADF) materials are promising for organic light-emitting diodes (OLEDs) owing to their narrowband emission and efficient triplet utilization. However, realizing stable deep-blue emission with high practical efficiency remains challenging, largely due to limited strategies for hypsochromic shifts without compromising photophysical properties. Here, we report a late-stage direct double borylation strategy for B/N-based MR frameworks, which extends π-conjugation resonance, increases transition energy, enhances transition dipole moment, and reduces the S<sub>1</sub>-T<sub>1</sub> energy gap. The proof-of-concept emitter, ν-DABNA-M-B-Mes, exhibits blue-shifted emission compared to its parent molecule while maintaining excellent TADF characteristics, including high photoluminescence quantum yield (93%), narrowband emission (16 nm), and fast reverse intersystem crossing rate (2.05 × 10<sup>5 </sup>s<sup>-1</sup>). OLEDs employing ν-DABNA-M-B-Mes achieve outstanding performance with >30% external quantum efficiency, high luminous efficacy, and near NTSC color purity. Furthermore, phosphor-sensitized fluorescence device display a minimal efficiency roll-off and long operational lifetime (LT<sub>80</sub> > 1000 h at 100 cd m<sup>-2</sup>), establishing a new benchmark for blue OLEDs.