Biomass-Derived Polysilsesquioxane Nanofilament Reinforced Porous Aerogel for Durable Passive Radiative Cooling across All Day and Weather Conditions.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41163436.
- Also identified by DOI 10.1021/acsnano.5c11008 and PMC identifier 12613843.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Passive radiative cooling (PRC) is a potentially sustainable strategy by reflecting sunlight (0.3-2.5 μm) and emitting heat through the atmospheric window (8-13 μm) without energy consumption. However, challenges remain due to high sunlight irradiance (1000 W m<sup>-2</sup>) during the day. Our research addresses these challenges by incorporating one-dimensional polysilsesquioxane nanofilaments (1D PSNFs) into micro- and nanoporous biomass-derived aerogels, forming a three-dimensional framework. The designed sustainable aerogel cooler achieves greater than 97% sunlight reflection and thermal emission, resulting in a cooling power of 138.6 W m<sup>-2</sup> over 720 h, reducing ambient temperatures by 9 °C. In addition, the aerogel cooler demonstrates high thermal stability, low thermal conductivity (29.0 mW m<sup>-1</sup> K<sup>-1</sup>), superhydrophobicity (water contact angle ∼175°), low density (44.43 kg/m<sup>3</sup>), and a large surface area (137.84 m<sup>2</sup>/g). These features enable effective radiative cooling across various weather conditions, while also maintaining environmental sustainability.