Mechanically Robust 2D Magnetic Semiconductor: Anisotropic Elasticity and Fatigue Resistance in CrSBr.
basic_science · Level V
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- Record sourced from PubMed, PMID 41186034.
- Also identified by DOI 10.1021/acs.nanolett.5c04818.
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Abstract
Two-dimensional (2D) materials with intrinsic anisotropy offer unique opportunities for direction-dependent functionality, yet their mechanical anisotropy and long-term reliability remain largely unexplored. Here, we systematically investigate the layered magnetic semiconductor CrSBr, revealing strong in-plane elastic anisotropy (<i>E</i><sub><i>a</i></sub>/<i>E</i><sub>b</sub> = 1.43) from angle-resolved atomic force microscopy (AFM) nanoindentation and an out-of-plane modulus of ∼54 GPa from contact resonance AFM, indicative of robust interlayer coupling. Dynamic AFM loading demonstrates pronounced anisotropic fatigue, with superior endurance along the <i>b</i>-axis attributed to enhanced interlayer energy dissipation, consistent with friction measurements and first-principles calculations of interlayer sliding energy. Remarkably, despite its lower fracture strength, CrSBr exhibits fatigue lifetimes comparable to graphene and CVD-grown MoS<sub>2</sub> under normalized stress. These results establish CrSBr as a mechanically robust 2D magnetic semiconductor, where anisotropic bonding and interlayer coupling combined govern cyclic damage resistance.