Breaking the symmetry of high-entropy alloy surfaces for compressively strain-tuned oxygen reduction reaction.

He, Lin; Li, Menggang; Qiu, Longyu; Ren, Xue; Tian, Fenyang; Sheng, Jie; Liu, Yequn; Luo, Mingchuan et al. · Nat Commun · 2025

basic_science · Level V

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Abstract

A largely unexplored approach for optimizing surface strains on terrace-type catalysts is the break of atomic symmetry to release surface stress. The key challenge lies in how to implement this approach into practical nanocatalysts, in particular the promising high-entropy alloys (HEAs). Herein, we design and synthesize a series of HEA nanorings (NRs) with abundant terrace-type defects for oxygen reduction reaction (ORR) electrocatalysis. The asymmetry-triggered release of surface stress enables the modulation of compressive strain for optimizing the electronic structure. On the optimally-tuned PtPdFeCoNi HEA NRs, we achieve mass and specific activities of 0.99 A mg<sup>-1</sup><sub>platinum group metal (PGM)</sub> and 1.32 mA cm<sup>-2</sup><sub>PGM</sub> at 0.95 V versus reversible hydrogen electrode (vs. RHE), demonstrating a competitive performance. Experimental and theoretical investigations unveil that the stress-released compressive strain lowers the d-band center of Pt sites in HEA NRs, resulting in favorable desorption of oxygenated intermediates and thus accelerated ORR kinetics.