Ultrathin PtCu Nanosheets: A New Frontier in Highly Efficient and Durable Catalysts for the Oxygen Reduction Reaction.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41378784.
- Also identified by DOI 10.1021/acs.nanolett.5c04848 and PMC identifier 12904072.
- Licence recorded as CC BY-NC-ND.
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Abstract
Platinum-copper alloy nanosheets supported on carbon (PtCu NS/C) with well-defined (111) facets were synthesized via a scalable one-pot method, yielding ultrathin structures with thicknesses of ∼1 nm and lateral sizes of ∼10-15 nm. As catalysts for the oxygen reduction reaction (ORR), PtCu NS/C exhibited superior performance and durability compared to those of PtCu octahedral nanoparticles (PtCu NP/C) and commercial Pt/C. In half-cell measurements, PtCu NS/C achieved a mass activity of 5.61 A mg<sub>Pt</sub><sup>-1</sup> at 0.9 V<sub>RHE</sub> and an electrochemically active surface area (ECSA) of 94 m<sup>2</sup> g<sub>Pt</sub><sup>-1</sup>, significantly surpassing those of PtCu NP/C and Pt/C. In polymer electrolyte membrane fuel cells (PEMFCs), PtCu NS/C delivered a current density of 48 mA cm<sup>-2</sup> at 0.8 V, retaining 31 mA cm<sup>-2</sup> after 50 000 accelerated stress test cycles. The outstanding activity and stability are attributed to the nanosheet architecture, which provides a high surface-to-volume ratio, abundant (111) surface atoms, enhanced Pt utilization, and an enlarged interfacial contact region with the carbon support. These findings highlight the potential of two-dimensional PtCu nanosheets as highly efficient and durable ORR catalysts for PEMFCs.