Redox-Improved Self-Assembled Monolayers for Inverted Perovskite Solar Cells.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41387434.
- Also identified by DOI 10.1038/s41467-025-66421-4 and PMC identifier 12722204.
- Licence recorded as CC BY-NC-ND.
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Abstract
Inverted perovskite solar cells (pero-SCs) utilizing nickel oxide (NiO<sub>x</sub>)/self-assembled monolayer (SAM) as a hole transport layer (HTL) have demonstrated high power conversion efficiency (PCE). However, variations in the valence states of NiO<sub>x</sub> on the surface create complexity in the growth of a high-quality SAM HTL. To address these challenges, a new SAM molecule MeOF-4SHCz is synthesized and utilized to target the Ni<sup>3+</sup>-rich regions on the NiO<sub>x</sub> substrate. A redox reaction occurs at the interface and the oxidation product of MeOF-4SHCz forms a new S-O-Ni bonding at the Ni<sup>3+</sup>-rich regions. The application of the combined SAMs of MeOF-4SHCz and the regular SAM MeOF-4PACz can improve the overall coverage and uniformity of the SAM layer on NiO<sub>x</sub>. As a result, the optimized inverted pero-SCs based on this redox-improved (ROI)-SAM HTL of MeOF-4SHCz/MeOF-4PACz = 4:1 (w/w) achieve a high PCE of 26.5% (certified as 26.28%) and improved stability with T<sub>90</sub> > 1000 hours.